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Observation of an eg-derived Metallic Band at the Cs/SrTiO3 Interface by Polarization-dependent Photoemission Spectroscopy

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Publication date: Available online 26 January 2016
Source:Thin Solid Films
Author(s): Kazuma Akikubo, Iwao Matsuda, Didier Schmaus, Guillaume Marcaud, Ro-Ya Liu, Mathieu G. Silly, Fausto Sirotti, Marie D'Angelo
A metallic band having the d z 2 -symmetry was evidenced at the interface between a Cs film and the SrTiO3(001) substrate. The symmetry assignment was carried out with the dipole-transition selection rule, probed by polarization-dependent photoemission spectroscopy. The e g -derived state of the SrTiO3(001) crystal is likely to be a bonding state composed of Cs s-orbital and Ti d-orbital with the e g symmetry, as predicted theoretically.


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