From micro to nanocrystalline boron doped diamond applied to cadmium detection

Publication date: 1 March 2017
Source:Thin Solid Films, Volume 625
Author(s): André F. Sardinha, Tatiane M. Arantes, Fernando H. Cristovan, Neidenei G. Ferreira
Cadmium detection was investigated by Square Wave Anodic Stripping Voltammetry (SWASV) measurements by using boron doped diamond electrodes with different morphologies from micro to nanocrocrystalline grains as Boron Doped Diamond (BDD) and Boron Doped Nanocrystalline Diamond (BDND), respectively. The argon concentrations, in the argon/hydrogen ratio, used were 0, 50, 60, 70, and 80vol.%. SWASV technique was applied in 4×10⁻⁴ mol L⁻¹ ammonium acetate buffer pH4.2. The peak currents were measured for Cd²⁺ concentration ranging from 1 to 20μgL⁻¹. This change in film grain size and roughness affected how cadmium was deposited on the electrode surfaces, thus affecting its electroanalytical response from SWASV measurements as well as its selectivity. For all electrodes cadmium detection limits (DL) were lower than 1μgL⁻¹ while for BDND electrode DL reached 0.016μgL⁻¹. These values are lower than that required by the Brazilian Health Ministry for potable water (1μgL⁻¹) and confirm that diamond electrodes are a suitable mercury-free method to determine cadmium trace levels in water. A strong correlation between the electrode selectivity and its grain size also confirmed the best performance of BDND electrode.