Publication date: 1 March 2017
Source:Thin Solid Films, Volume 625
Author(s): G.R. Khan, K. Asokan, Bilal Ahmad
The phase transition temperature (T t ) across semiconductor-to-metal transition (SMT) of the vanadium dioxide (VO2 ) thin films can be tuned to room temperature either by reducing the grain size of crystallites to nanoscale or by doping them with molybdenum (Mo6 +) ions. In this work, the combined response of these effects (quantum size effect and doping mechanism) has been demonstrated by studying the structural and electrical transport properties of low concentration (0, 1, 3 and 5%) Mo6 +-doped VO2 nanofilms across SMT. Room temperature value of T t = 303.7 K was achieved for Mo6 +-doped VO2 nanofilms as compared to 333.2 K of pristine VO2 nanofilms and against 340 K of bulk VO2 thin films. A systematic analysis of charge carrier mobility (μ ), Seebeck coefficient (s ) and charge carrier concentration (n ) was performed for the first time to the best knowledge of the authors. Decrease in μ and increase in s were observed across SMT with increase in doping percentage of Mo6 +-ions. n increased by 1 to 4 orders of magnitude across SMT for the samples which contributed almost entirely for the resistance change. Resistance ratio (R s /R M ) and hysteresis width (ΔH ) diminished whereas hysteresis sharpness (ΔT ) escalated across SMT with the increase of Mo+ 6-ions.
Source:Thin Solid Films, Volume 625
Author(s): G.R. Khan, K. Asokan, Bilal Ahmad